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Foaming in CO2 sc medium as an efficient way to produce electromagnetic interference shielding materials

Abstract

This communication reports on the preparation of novel nanocomposites foams that are efficient broadband microwave absorbers.7 Multiwalled carbon nanotubes (MWNT) are first successfully dispersed into polymer matrix by melt-blending as confirmed by TEM microscopy and rheology. Then foaming of these nanocomposites8 occurs under supercritical CO2 conditions by a two-step process.9 This physical foaming constitutes a green alternative to classical foaming agents.10 Well-defined microcellular foams11 were obtained with cell size around 10-50 μm and cellular density around 108 cells per cm3, the morphology of the foam was determined by SEM microscopy. The impact of several criteria on the morphology of the foam will be discussed. The EMI shielding efficiency of these materials are then evaluated and compared to the non-foamed nanocomposites. Finally, we will discuss about the design of the foam that is essential to optimize the performances of the EMI absorber

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