We study the magnetic properties of nanometer-sized graphene structures with
triangular and hexagonal shapes terminated by zig-zag edges. We discuss how the
shape of the island, the imbalance in the number of atoms belonging to the two
graphene sublattices, the existence of zero-energy states, and the total and
local magnetic moment are intimately related. We consider electronic
interactions both in a mean-field approximation of the one-orbital Hubbard
model and with density functional calculations. Both descriptions yield values
for the ground state total spin, S, consistent with Lieb's theorem for
bipartite lattices. Triangles have a finite S for all sizes whereas hexagons
have S=0 and develop local moments above a critical size of ≈1.5 nm.Comment: Published versio