Oscillatory squeeze flow for the study of linear viscoelastic behavior

Abstract

The squeezing of a sample between parallel plates has been used for many years to characterize the rheological behavior of soft, purely viscous materials, and in recent times, small-amplitude oscillatory squeezing has been proposed as a means to determine the linear viscoelastic properties of molten polymers and suspensions. The principal advantage of squeeze flow rheometer over rotational devices is the simplicity of the apparatus. It has no air bearing and is much less expensive and easier to use. Accuracy may be somewhat reduced, but for quality control purposes, it could be quite useful. It might also find application as the central component of a high-throughput rheometer for evaluating experimental materials. The deformation is not simple shear, but equations have been derived to show that the oscillatory compressive (normal) force that is measured can serve as a basis for calculating the storage and loss moduli. These theories as well as instruments that have been developed to generate the required deformation are described, and applications to a variety of materials are described

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