GA Swile

JR Hall

NS Ham

A quantitative analysis of
the variable-temperature 1H N.M.R. spectra of acetylacetonatotrimethyl-platinum(IV)
has been made. In CDCl3 solution the exchange of acetylacetonate
ligands is a first-order reaction and proceeds predominantly by dissociation of
the dimer into two separated five-coordinate activated complexes. The
activation energy is 61.5 � 0.8 kJ mol-1.





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Australian Journal of Chemistry

N.M.R. studies of ligand exchange on acetylacetonatotrimethylplatinum(IV)

http://www.publish.csiro.au/ch/pdf/ch9750759

N.M.R. studies of ligand exchange on acetylacetonatotrimethylplatinum(IV)

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