C L L Chai

G Lowe

W A Loughlin

Phenyl [(R)-16O,17O,18O]sulphate was synthesized and used to study the stereochemical course of sulphuryl transfer to p-cresol catalysed by arylsulphatase II from Aspergillus oryzae. The reaction was shown to proceed with retention of configuration at the sulphur atom, providing evidence for the involvement of a sulpho-enzyme intermediate on the reaction pathway.</jats:p

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Biochemical Journal

The stereochemical course of sulphuryl transfer catalysed by arylsulphatase II from <i>Aspergillus oryzae</i>

http://www.biochemj.org/content/ppbiochemj/287/3/805.full.pdf

The stereochemical course of sulphuryl transfer catalysed by arylsulphatase II from Aspergillus oryzae

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