Phase-field analysis of quenching and partitioning in a polycrystalline Fe-C system under constrained-carbon equilibrium condition

Abstract

Mechanical properties of steels are significantly enhanced by retained austenite. Particularly, it has been shown that a recently developed heat-treatment technique called Quenching and Partitioning (Q\&P) stabilises austenite effectively. In the present work, the phase-field approach is adopted to simulate the phase transformation and carbon diffusion, which respectively accompanies the quenching and partitioning process of the polycrystalline Fe-C system. By incorporating the chemical driving-force from the CALPHAD database, the elastic phase-field model, which recovers the sharp-interface solutions, simulates the martensite (alpha') transformation at three different quenching temperatures. The resulting martensite volume-fractions are in complete agreement with the analytical predictions. For the first time, in this study, the constrained carbon equilibrium (CCE) condition is introduced in the polycrystalline set-up to yield the predicted partitioning endpoints. Under the CCE condition, the carbon partitioning in two alloys of varying composition is analysed through the phase-field model which employs chemical potential as the dynamic variable. The volume fraction and distribution of retained austenite is determined from the carbon distribution and its temporal evolution during the partitioning is investigated. It is identified that in the initial stages of partitioning carbon gets accumulated in the austenite ($\gamma$) along the $\gamma\alpha'$-interface, owing to the substantial difference in the diffusivities and CCE endpoints. This accumulation stabilises the austenite adjacent to the interface. However, depending on the martensite volume-fraction and the alloy composition, the evolution of the stabilised austenite varies. Furthermore, the influence of the phase distribution on the kinetics of the temporal evolution of retained austenite is elucidated