Great attention has been drawn to topological superconductivity due to its
potential application in topological quantum computing. Meanwhile, pressure is
regarded as a powerful tool for tuning electronic structure and even inducing
superconductivity in topological insulators. As a well-defined topological
insulator, Bi2Te2.1Se0.9 can be a suitable candidate to search for topological
superconductivity and study its intrinsic property. In this paper, we report
the occurrence of superconductivity and electronic topological transition (ETT)
in Bi2Te2.1Se0.9 with applied pressure. Superconductivity can be observed at
2.4 GPa with the Tconset around 6.6 K in Bi2Te2.1Se0.9 by resistance
measurement, and the corresponding structure resolved by X-ray diffraction and
Raman experiments doesn't change below the pressure of 8.4 GPa. Moreover, at
about 3.0 GPa, the abnormal changes of c/a as well as the full width at half
maximum (FWHM) of mode indicate the occurrence of electronic topological
transition (ETT). These results indicate that superconductivity can be realized
in doped topological insulator Bi2Te2.1Se0.9 in the low-pressure rhombohedral
phase