Given a function f:(0,\infty)\rightarrow\RR and a positive semidefinite
n×n matrix P, one may define a trace functional on positive definite
n×n matrices as A\mapsto \Tr(Pf(A)). For differentiable functions
f, the function A\mapsto \Tr(Pf(A)) is differentiable at all positive
definite matrices A. Under certain continuity conditions on~f, this
function may be extended to certain non-positive-definite matrices A, and the
\emph{directional} derivatives of \Tr(Pf(A) may be computed there. This note
presents conditions for these directional derivatives to exist and computes
them. These conditions hold for the function f(x)=log(x) and for the
functions fp(x)=xp for all p>−1. The derivatives of the corresponding
trace functionals are computed here