Algorithms are introduced that produce optimal Markovian couplings for large finite-state-space discrete-time Markov chains with sparse transition matrices; these algorithms are applied to some toy models motivated by fluid-dynamical mixing problems at high Peclét number. An alternative definition of the time-scale of a mixing process is suggested. Finally, these algorithms are applied to the problem of coupling diffusion processes in an acute-angled triangle, and some of the simplifications that occur in continuum coupling problems are discussed
