Sherpa Romeo green journal7-Phenyl- 124324b'2,524-trithia-2,4,6,8,9-penta -
azabicyclo[3.3.1]nonane, CTHsNsS 3, M r = 255.3,
monoclinic, P2Jn, a = 5.958 (1), b = 22.954 (2), c=
7.428 (1) A,/I= 106.25 (1) °, V= 975.2 (4) A 3, Z=4,
D x = 1.74 g cm -3, 2(Mo K~) = 0.71073 A, /~ =
7.00 cm -l, F(000) = 520, T = 293 K, R = 0.030 for
1363 unique observed reflections. The planar SNCNS
and SNSNS components of the bicyclic molecule make
dihedral angles of 137.1 and 118.3 ° with the SNS
bridging unit. The S-N bonds connecting the NSN
fragment to the CN3S 2 ring are much longer (1.728 A)
than those in the remainder of the molecule (1.546-
1.630 A).Ye
