The mixed chloride-azide [ZnL(N3)1.65Cl0.35] (1) and chloride-isocyanate [CdL(NCO)1.64Cl0.36] (2)
complexes have been prepared in the reactions of (E)-N,N,N-trimethyl-2-oxo-2-(2-(quinolin-2-
ylmethylene)hydrazinyl)ethan-1-aminium chloride (HLCl) and the corresponding Zn2+ and Cd2+
salts by adding the NaN3 and NaOCN, respectively. The structures of complexes 1 and 2 were
determined by X-ray crystallography

Anđelković, Katarina K.

Keškić, Tanja

Milenković, Milica R.

Radanović, Dušanka D.

Čobeljić, Božidar

English

Faculty of Chemistry Repository - Cherry

TWENTIETH ANNUAL CONFERENCEYUCOMAT 2018Hunguest Hotel Sun Resort Herceg Novi, Montenegro,September 3-7, 2018http://www.mrs-serbia.org.rsProgrammeandThe Book of AbstractsOrganised by:Materials Research Society of SerbiaEndorsed by:Materials Research Society,European Materials Research SocietyandFederation of European Material SocietiesTitle: THE TWENTIETH ANNUAL CONFERENCEYUCOMAT 2018Programme and The Book of AbstractsPublisher: Materials Research Society of SerbiaKnez Mihailova 35/IV, P.O.Box 433, 11000 Belgrade, SerbiaPhone: +381 11 2185-437http://www.mrs-serbia.org.rsEditors: Prof. Dr. Dragan P. Uskoković and Prof. Dr. Velimir R. RadmilovićTechnical editor: Sava StoisavljevićFront cover: Modified Photo by Hons084; Wikimedia Commons(https://commons.wikimedia.org/wiki/File:Widoki_z_twierdzy_Forte_Mare_na_Herceg_Novi_03.jpg); CC BY-SA 4.0Back cover: Modified Photo by Dani Lavi 0007; Wikimedia Commons(https://commons.wikimedia.org/wiki/File:Belgrade_at_night.jpg); CC BY-SA 4.0Copyright  2018 Materials Research Society of SerbiaAcknowledgments: This conference is celebrating 20 years of YUCOMATPrinted in: Biro KontoSutorina bb, Igalo – Herceg Novi, MontenegroPhones: +382-31-670123, 670025, E-mail: bkonto@t-com.meCirculation: 220 copies. The end of printing: August 2018TWENTIETH ANNUAL CONFERENCEYUCOMAT 2018Herceg Novi, September 3-7, 2018141P.S.E.19.Crystal structures of mixed chloride-azide zinc (II) and chloride-isocyanate cadmium (II)complexes with the condensation product of 2-quinolinecarboxaldehyde and girard’sreagentTanja Keškić1, Milica Milenković1, Božidar Čobeljić1, Dušanka Radanović 2,Katarina Anđelković11Faculty of Chemistry, University of Belgrade, Studentski trg 12–16, 11000 Belgrade, Serbia;2Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Njegoševa 12,P.O. Box 815, 11000 Belgrade, SerbiaThe mixed chloride-azide [ZnL(N3)1.65Cl0.35] (1) and chloride-isocyanate [CdL(NCO)1.64Cl0.36] (2)complexes have been prepared in the reactions of (E)-N,N,N-trimethyl-2-oxo-2-(2-(quinolin-2-ylmethylene)hydrazinyl)ethan-1-aminium chloride (HLCl) and the corresponding Zn2+ and Cd2+salts by adding the NaN3 and NaOCN, respectively. The structures of complexes 1 and 2 weredetermined by X-ray crystallography.In complexes 1 and 2, Zn1 and Cd1 ions, respectively, are five-coordinated in a distorted squarebased pyramidal geometry with NNO set of donor atoms of deprotonated hydrazone ligand andtwo monodentate ligands N3– and/or N3– and Cl– in the case of 1 and OCN– and/or OCN– and Cl–in the case of 2.Acknowledgements: This work was supported by the Ministry of Education, Science andTechnological development of the Republic of Serbia (Grant OI 172055).CIP- Каталогизација у публикацијиНародна библиотека Србије66.017/.018(048)MATERIALS Research Society of Serbia (Beograd). Conference (20 ; 2018 ; HercegNovi) Programme ; and The Book of Abstracts / Twentieth Annual ConferenceYUCOMAT 2018, Herceg Novi, September 3-7, 2018 ; organised by Materials ResearchSociety of Serbia ; [editors Dragan P. Uskoković and Velimir R. Radmilović]. - Belgrade :Materials Research Society of Serbia, 2018 (Herceg Novi : Biro Konto). - XLIV, 159 str. :ilustr. ; 23 cmTiraž 220. - Bibliografija uz pojedine apstrakte. - Registar.ISBN 978-86-919111-3-31. Materials Research Society of Serbia (Beograd)a) Наука о материјалима - Апстрактиb) Технички материјали - АпстрактиCOBISS.SR-ID 266944524

Crystal structures of mixed chloride-azide zinc (II) and chloride-isocyanate cadmium (II) complexes with the condensation product of 2-quinolinecarboxaldehyde and girard’s reagent

Cherry - Repository of the Faculty of Chemistry;  University of Belgrade


TWENTIETH ANNUAL CONFERENCE
YUCOMAT 2018
Hunguest Hotel Sun Resort Herceg Novi, Montenegro,
September 3-7, 2018
http://www.mrs-serbia.org.rs
Programme
and
The Book of Abstracts
Organised by:
Materials Research Society of Serbia
Endorsed by:
Materials Research Society,
European Materials Research Society
and
Federation of European Material Societies
Title: THE TWENTIETH ANNUAL CONFERENCE
YUCOMAT 2018
Programme and The Book of Abstracts
Publisher: Materials Research Society of Serbia
Knez Mihailova 35/IV, P.O.Box 433, 11000 Belgrade, Serbia
Phone: +381 11 2185-437
http://www.mrs-serbia.org.rs
Editors: Prof. Dr. Dragan P. Uskoković and Prof. Dr. Velimir R. Radmilović
Technical editor: Sava Stoisavljević
Front cover: Modified Photo by Hons084; Wikimedia Commons
(https://commons.wikimedia.org/wiki/File:Widoki_z_twierdzy_Forte_Mare_na_Herceg_Novi_03
.jpg); CC BY-SA 4.0
Back cover: Modified Photo by Dani Lavi 0007; Wikimedia Commons
(https://commons.wikimedia.org/wiki/File:Belgrade_at_night.jpg); CC BY-SA 4.0
Copyright  2018 Materials Research Society of Serbia
Acknowledgments: This conference is celebrating 20 years of YUCOMAT
Printed in: Biro Konto
Sutorina bb, Igalo – Herceg Novi, Montenegro
Phones: +382-31-670123, 670025, E-mail: bkonto@t-com.me
Circulation: 220 copies. The end of printing: August 2018
TWENTIETH ANNUAL CONFERENCE
YUCOMAT 2018
Herceg Novi, September 3-7, 2018
141
P.S.E.19.
Crystal structures of mixed chloride-azide zinc (II) and chloride-isocyanate cadmium (II)
complexes with the condensation product of 2-quinolinecarboxaldehyde and girard’s
reagent
Tanja Keškić1, Milica Milenković1, Božidar Čobeljić1, Dušanka Radanović 2,
Katarina Anđelković1
1Faculty of Chemistry, University of Belgrade, Studentski trg 12–16, 11000 Belgrade, Serbia;
2Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Njegoševa 12,
P.O. Box 815, 11000 Belgrade, Serbia
The mixed chloride-azide [ZnL(N3)1.65Cl0.35] (1) and chloride-isocyanate [CdL(NCO)1.64Cl0.36] (2)
complexes have been prepared in the reactions of (E)-N,N,N-trimethyl-2-oxo-2-(2-(quinolin-2-
ylmethylene)hydrazinyl)ethan-1-aminium chloride (HLCl) and the corresponding Zn2+ and Cd2+
salts by adding the NaN3 and NaOCN, respectively. The structures of complexes 1 and 2 were
determined by X-ray crystallography.
In complexes 1 and 2, Zn1 and Cd1 ions, respectively, are five-coordinated in a distorted square
based pyramidal geometry with NNO set of donor atoms of deprotonated hydrazone ligand and
two monodentate ligands N3– and/or N3– and Cl– in the case of 1 and OCN– and/or OCN– and Cl–
in the case of 2.
Acknowledgements: This work was supported by the Ministry of Education, Science and
Technological development of the Republic of Serbia (Grant OI 172055).
CIP- Каталогизација у публикацији
Народна библиотека Србије
66.017/.018(048)
MATERIALS Research Society of Serbia (Beograd). Conference (20 ; 2018 ; Herceg
Novi)
 Programme ; and The Book of Abstracts / Twentieth Annual Conference
YUCOMAT 2018, Herceg Novi, September 3-7, 2018 ; organised by Materials Research
Society of Serbia ; [editors Dragan P. Uskoković and Velimir R. Radmilović]. - Belgrade :
Materials Research Society of Serbia, 2018 (Herceg Novi : Biro Konto). - XLIV, 159 str. :
ilustr. ; 23 cm
Tiraž 220. - Bibliografija uz pojedine apstrakte. - Registar.
ISBN 978-86-919111-3-3
1. Materials Research Society of Serbia (Beograd)
a) Наука о материјалима - Апстракти
b) Технички материјали - Апстракти
COBISS.SR-ID 266944524


http://cherry.chem.bg.ac.rs/bitstream/id/6376/Keskic_YUCOMAT-2018.pdf

Crystal structures of mixed chloride-azide zinc (II) and chloride-isocyanate cadmium (II) complexes with the condensation product of 2-quinolinecarboxaldehyde and girard’s reagent

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