222Rn is a naturally occurring noble gas produced via alpha decay of 226Ra and it is the only gaseous daughter
product of the decay chain of 238U, a radioisotope present in the majority of soils and rocks. 222Rn is almost
chemically inert, it exhales into the atmosphere and migrates by diffusion and convection: as it runs out mainly
through radioactive decay characterized by a 3.82 days half-life, it is a widespread atmospheric tracer, particularly
effective for gathering insights into air vertical mixing processes in the atmospheric boundary layer. Understanding
222Rn distribution in the environment is also of great concern for investigating the health impacts of low-level
radioactivity and for supporting regulation of human exposure to ionizing radiation in modern society.
Airborne Gamma-Ray Spectroscopy (AGRS) always treated 222Rn as a source of background: its decay product
214Bi is the main gamma-emitter in the 238U decay chain and, since it binds to airborne aerosols, it is responsible
for the measured radon background. For the first time we exploit the AGRS method for quantifying the presence
of 222Rn in the atmosphere and assessing its vertical profile. AGRS measurements have been performed in the
(70 – 3000) m altitude range during a ~4 hours survey over the Tyrrhenian sea. The experimental setup, made up
of four 4L NaI(Tl) crystals, was mounted on the Radgyro, a prototype aircraft designed for multisensorial acquisitions
in the field of proximal remote sensing. A theoretical model accounting for the presence of atmospheric
222Rn has been developed in order to reconstruct experimental radiometric data over the entire altitude range: the
overall count rate recorded in the 214Bi photopeak is fitted as a superposition of a constant component due to the
radioactivity of the aircraft and of the equipment plus a height dependent contribution due to cosmic radiation
and atmospheric 222Rn. Modeling the latter component requires a radon vertical profile, which is in turn directly
connected with the dynamics of the atmospheric boundary layer. Thanks to the large elevation extent, it has been
possible to explore the presence of radon in the atmosphere via the modeling of the count rate in the 214Bi photopeak
energy window according to two analytical models which respectively exclude and account for the presence
of atmospheric radon. The refined statistical analysis provides not only a conclusive evidence of AGRS 222Rn
detection but also a (0.96 ± 0.07) Bq/m^3 222Rn concentration and a (1318 ± 22) m atmospheric layer depth fully
compatible with literature data