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AgandCuloadedonTiO2/graphite as a catalyst for �Escherichia coli- contaminated water disinfection

Abstract

TiO2 film was synthesized by means of the chemical bath deposition (CBD) method from TiCl4 as a precursor and surfactant cetyl trimethyl ammonium bromide (CTAB) as a linking and assem- bling agent of the titanium hydroxide network on a graphite substrate. Ag and Cu were loaded on the TiO2 film by means of electrodeposition at various applied currents. Photoelectrochemical testing on the composite of Ag–TiO2/G and Cu–TiO2/G was used to define the composite for Escherichia coli-contaminated water disinfection. Disinfection efficiency and the rate of disinfection of E. coli-contaminated water with Ag–TiO2/G as a catalyst was higher than that observed for Cu–TiO2/G in all disinfection methods including photocatalysis (PC), electrocatalysis (EC), and photoelectrocatalysis (PEC). The highest rate constant was achieved by the PEC method using Ag–TiO2/G, k was 6.49 × 10−2 CFU mL−1 min−1 . Effective disinfection times of 24 h (EDT24) and 48 h (EDT48) were achieved in all methods except the EC method using Cu–TiO2/G. Keywords: Ag–TiO2/G, Cu–TiO2/G, Escherichia coli, disinfectio

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