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多孔NiCr在750℃ NaCl沉积盐中的热腐蚀机理研究
Authors
兰昊
张伟刚
+4 more
房师阁
杨滨
陈凌云
黄传兵
Publication date
1 January 2017
Publisher
Abstract
针对飞机发动机高压压气机NiCr系可磨耗封严涂层发生的NaCl热沉积盐高温腐蚀现象,采用粉末烧结法制备了多孔80Ni20Cr合金,研究了其在750℃空气气氛中的NaCl热腐蚀行为。采用X射线衍射和能谱分析等技术对腐蚀产物进行了分析。结果表明,NaCl固体盐通过阻碍合金表面生成连续致密的Cr_2O_3,加速多孔NiCr的腐蚀和氧化。研究发现,在样品外表面形成的Cr_2O_3、NiO、NiCr_2O_4混合氧化物膜易开裂剥落,是合金加速腐蚀的主要方式。此外,通过同步热分析并结合热力学模拟计算发现,NiCr合金的热腐蚀由氯化-氧化协同控制,初始依靠NaCl与Cr元素反应引发合金的循环腐蚀,并推动整个腐蚀过程不断进行。</p
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Last time updated on 08/09/2018