Oxidation kinetics of platinum modified aluminide and overlay coatings on nickel base superalloys were investigated. Isothermal oxidation tests were carried out at 1050°C in synthetic air. Cyclic oxidation tests were performed with 2 cycle frequencies :
- Short term cycles : 1h dwells at 1050°C in synthetic air ×1800 cycles
- Long term cycles : 300h dwells at 1050°C in laboratory air × 6 cycles (experiment planned to totalize at least 10 000 hours at high temperature)
The mass gain curves point out a large effect of the cycle frequency at 1050°C for overlay NiCoCrAlYTa coating whereas the effect is less significant for Pt-modified nickel aluminide coating. Scanning electron microscopy combined with energy dispersive X-ray spectroscopy was used to evaluate the effect of cycle frequency on microstructural evolution. A simple statistical spalling model [1,2], assuming that the parabolic rate constant kp and the spalling probability p are constant, is tentatively applied and discussed in view of the microstructural evolution complexity