A. W. Jasper, S. Nangia, C. Zhu and D. G. Truhlar, Acc. Chem. Res. 39D. A. McCormack and K. F. Lim, Phys. Chem. Chem. Phys. 1Author Institution: Department of Chemistry, University of Minnesota, 207 Pleasant Street S.E., Minneapolis, MN 55455-0431, USAThe photodissociation dynamics of ammonia upon excitation of the out-of-plane bending mode (mode ν2 with n2=0,..,6 quanta of vibration) on its \~A electronic state is investigated by means of several semiclassical methods and compared to experiments. Five semiclassical methods are tested: one mean-field approach (the CSDM method), two surface-hopping methods (the FSTU and FSTU/SD methods) and two surface-hopping methods with zero-point energy preservation (the FSTU/SD/TRAPZ and FSTU/SD/mTRAPZ methods).}, 101 (2006); A. W. Jasper and D. G. Truhlar, J. Chem. Phys. \textbf{127}, 194306 (2007); D. Bonhommeau and D. G. Truhlar (in preparation)} We found a qualitative difference between distributions obtained for n2=0 and n2>1 which is experimentally observed. Distributions obtained for n2=1 present an intermediate behavior between distributions obtained for smaller and larger n2 values. The dynamics is also found to be highly electronically nonadiabatic with all these methods. NH2 internal energy distributions may have a negative energy tail when the zero-point energy (ZPE) conservation is not ensured throughout the dynamics. Unlike the original TRAPZ (TRAjectory Projection onto Zero-point energy orbits) method,}, 1 (1999)} the mTRAPZ (modified TRAPZ) method does not lead to unphysical results and is much less time consuming. The effect of including ZPE corrections in semiclassical dynamics is also discussed in terms of agreement with experimental findings