DETECTION OF ATMOSPHERICALLY RELEVANT HYDROCARBONS BY DIODE LASER CAVITY RINGDOWN SPECTROSCOPY

Abstract

Author Institution: Diagnostic Instrumentation and Analysis Laboratory, Mississippi State University, Starkville, MS 39759; Chemistry Department, State University of New York, College of Environmental Science and Forestry, Syracuse, NY 13210The first overtones of the asymmetric CH stretch of 2-methyl-1,3-butadiene (isoprene), 2,3-dimethyl-1,3-butadiene and 1,3-butadiene were observed in gas phase. The absorption was monitored by means of continuous wave Cavity Ring Down Spectroscopy (cw CRDS) at room temperature. A near infrared diode laser was employed as a light source. The absorption cross-section was determined at 1651.5 nm. This study is a starting point for future studies of the peroxy radicals formed in the OH-initiated degradation of these atmospherically relevant compounds. The preliminary estimates of the absorption cross-section are 2.88 x $10^{-22}$ cm$^{2}$ for 2,3-dimethyl-1,3-butadiene and 7.22 x $10^{-22}$ cm$^{2}$ for isoprene, respectively. The NIR absorption cross-sections for isoprene will be calibrated using the known UV absorption cross-section