Grid resources such as data, services, and equipment, are increasingly being annotated with descriptive metadata that facilitates their discovery and their use in the context of Virtual Organizations (VO). Making such growing body of metadata explicit and available to Grid services is key to the success of the VO paradigm. In this paper we present a model and management architecture for Semantic Bindings, i.e., firstclass Grid entities that encapsulate metadata on the Grid and make it available through predictable access patterns. The model is at the core of the S-OGSA reference architecture for the Semantic Grid