We present results for many-body perturbation theory for the one-body Green's
function at finite temperatures using the Matsubara formalism. Our method
relies on the accurate representation of the single-particle states in standard
Gaussian basis sets, allowing to efficiently compute, among other observables,
quasiparticle energies and Dyson orbitals of atoms and molecules. In
particular, we challenge the second-order treatment of the Coulomb interaction
by benchmarking its accuracy for a well-established test set of small
molecules, which includes also systems where the usual Hartree-Fock treatment
encounters difficulties. We discuss different schemes how to extract
quasiparticle properties and assess their range of applicability. With an
accurate solution and compact representation, our method is an ideal starting
point to study electron dynamics in time-resolved experiments by the
propagation of the Kadanoff-Baym equations.Comment: 12 pages, 8 figure