Stable polyyne chains terminated with biphenyl end groups
(a,u-biphenylpolyynes) were synthesized in a single step through a simple
procedure by using the Cadiot-Chodkiewicz reaction conditions. The
a,ubiphenylpolyynes were separated through HPLC analysis and identified by
means of their electronic absorption spectra. The a,u-biphenylpolyynes were
studied by FT-IR and Raman spectroscopy and the spectral interpretation was
supported with DFT calculations. A peculiarly low reactivity of
a,u-biphenylpolyynes with ozone was observed.Comment: The research leading to these results has received funding from the
European Research Council Consolidator Grant EspLORE (ERC-2016-CoG Grant
No.724610
