Versatile Postmodification
of Conjugated Microporous
Polymers Using Thiol-yne Chemistry
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Abstract
Radical thiol-yne chemistry is used for the modification
of microporous
networks with aliphatic alcohols. The degree of functionalization
can be tuned by varying the reacted amount of thiol. Porosity analysis
indicates that the microporosity can be preserved within a certain
range, however, a decrease in pore size is observed