Synthesis and Structure
of Distanna and Tristanna
Ansa Half-Sandwich Complexes of Ruthenium and Nickel
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Abstract
The synthesis and structural characterization of the
first tin-bridged
ansa half-sandwich complexes via a two-step protocol from Na[η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>Ru(CO)<sub>2</sub>] and in situ
generated Na[η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>Ni(CO)]
are presented. Both compounds are characterized by multinuclear NMR
spectroscopy and single-crystal diffraction
