Rhodium-Catalyzed Asymmetric
Conjugate Addition of
Arylboronic Acids to Nitroalkenes Using Olefin–Sulfoxide Ligands
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Abstract
An efficient rhodium/olefin–sulfoxide catalyzed
asymmetric
conjugate addition of organoboronic acids to a variety of nitroalkenes
has been developed, where 2-methoxy-1-naphthyl sulfinyl functionalized
olefin ligands have shown to be highly effective and are applicable
to a broad scope of aryl, alkyl, and heteroaryl nitroalkenes