Structure of [C₄mpyr][NTf₂] Room-Temperature Ionic Liquid at Charged Gold Interfaces

Abstract

The structure of 1-butyl-1-methylpyrrolidinium bis­(trifluoromethylsulfonyl)­imide ([C₄mpyr]­[NTf₂]) room-temperature ionic liquid at an electrified gold interface was studied using neutron reflectometry, cyclic voltammetry, and differential capacitance measurements. Subtle differences were observed between the reflectivity data collected on a gold electrode at three different applied potentials. Detailed analysis of the fitted reflectivity data reveals an excess of [C₄mpyr]⁺ at the interface, with the amount decreasing at increasingly positive potentials. A cation rich interface was found even at a positively charged electrode, which indicates a nonelectrostatic (specific) adsorption of [C₄mpyr]⁺ onto the gold electrode