Electrospinning Synthesis
of Wire-Structured LiCoO<sub>2</sub> for Electrode Materials of High-Power
Li-Ion Batteries
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Abstract
An application of the Li-ion batteries to advanced transportation
systems essentially requires the enhancement of the rate capability;
thus, the fabrication of nanostructured cathode materials with the
large surface area and short Li-ion diffusion length is particularly
important. In this study, an electrospinning method was adopted for
the synthesis of wire-structured LiCoO<sub>2</sub>. The diameter of
the as-spun fiber obtained from the precursor solution with multiwalled
carbon nanotubes (vapor-grown carbon fiber, VGCF) was thinner than
that of as-spun fiber obtained from the solution without VGCF. After
the heat treatment, wire-structured LiCoO<sub>2</sub> was successfully
obtained regardless of the existence of dispersed VGCF in the precursor
solution, although the particle size of LiCoO<sub>2</sub> fabricated
with VGCF was smaller than that of LiCoO<sub>2</sub> fabricated without
VGCF. The charge/discharge and rate-capability experiments revealed
that both resulting materials show the reversible Li-ion insertion/extraction
reaction. However, due to the existence of a small irreversible capacity
at the initial cycles, the interfacial resistance increases, resulting
in the poor cyclability and lower charge/discharge rate capability,
especially for nanowire LiCoO<sub>2</sub> fabricated with VGCF