Metal-Controlled Diastereoselective Self-Assembly and Circularly Polarized Luminescence of a Chiral Heptanuclear Europium Wheel

Abstract

The chiral dissymmetric tetradentate ligand (<i>S</i>)-6′-(4-phenyloxazolin-2-yl)-2,2′-bipyridine-6-carboxylate (S-Phbipox) leads to the diastereoselective assembly of a homochiral Eu³⁺ triangle and a highly emissive (quantum yield = 27%) heptanuclear wheel that is the largest example of a chiral luminescent complex of Eu³⁺ reported to date. The nuclearity of the assembly is controlled by the solvent and the Eu³⁺ cation. All of the compounds show large circularly polarized luminescence with an activity that varies with the nature of the assembly (highest for the homochiral trimer)