Viscoelastic and Photoresponsive
Properties of Microparticle/Liquid-Crystal
Composite Gels: Tunable Mechanical Strength along with Rapid-Recovery
Nature and Photochemical Surface Healing using an Azobenzene Dopant
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Abstract
We investigated viscoelastic and photoresponsive properties
of
the microparticle/liquid-crystal (LC) composite gels. The mechanical
strength of the colloidal gels can be widely tuned by varying particle
concentrations. With increasing particle concentration, a storage
modulus of the particle/LC composite gels increased and reached over
10<sup>4</sup> Pa, showing good self-supporting ability. We demonstrated
for the first time that the particle/LC composite gels exhibited rapid
and repetitive recovery of the mechanical strength after large-amplitude
oscillatory breakdown. In addition, photoresponsive properties of
the composite gels were investigated by the <i>cis</i>–<i>trans</i> photoisomerization of the azobenzene compound doped
into the host LCs. The photochemical gel–sol transition could
be repeatedly induced by changing the phase structure of the host
LCs between nematic and isotropic, using the photoisomerization. The
particle/LC composite gels can be applied to optically healable materials
by the site-selective gel–sol transition based on the photochemical
modulation of the phase structures of the host LCs