Targeted Synthesis of
Heterobimetallic Compounds Containing
a Discrete Vanadium(V)−μ-Oxygen–Iron(III) Core
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Abstract
Heterobimetallic compounds [L<sup>1</sup>OV<sup>V</sup>O→Fe(metsalophen)(H<sub>2</sub>O)] (<b>1</b>) and [L<sup>2</sup>OV<sup>V</sup>O→Fe(metsalophen)(H<sub>2</sub>O)]CH<sub>3</sub>CN (<b>2</b>), where H<sub>2</sub>L<sup>1</sup> and H<sub>2</sub>L<sup>2</sup> are tridentate dithiocarbazate-based
Schiff base ligands, containing a discrete V<sup>V</sup>–μ-O–Fe<sup>III</sup> angular core have been synthesized for the first time through
a targeted synthesis route: confirmation in favor of such a heterobimetallic
core structure has come from single-crystal X-ray diffraction analysis
and electrospray ionization mass spectrometry
