Tip Shaping for ZnO Nanorods
via Hydrothermal Growth
of ZnO Nanostructures in a Stirred Aqueous Solution
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Abstract
To enhance the field emission (FE) properties of emitters
based
on ZnO nanostructures, the growth of ZnO nanostructures on ZnO nanorods
(NRs) (1–1.2 μm in length and ∼200 nm in diameter)
in a disturbed
hydrothermal growth (HTG) solution is demonstrated. Experimental results
reveal that the degree of disturbance of the aqueous solution determines
both the shape and location of the synthesized ZnO nanostructures.
For stirring speeds of 300 and 600 rpm (rpm), NR-like ZnO nanostructures
with a reduced
uniform diameter (70–120 nm) and a tapered shape but a rough
surface are grown on the basal
plane of ZnO NRs, respectively. For stirring speeds of 900 and 1150
rpm, ZnO needles (40–70 nm and 15–20 nm in diameter,
respectively) were synthesized along the {101̅0}
planes of the ZnO NRs with coherent c-planes. FE characteristics of
ZnO-NRs emitters with and without the second stage growth of ZnO nanostructures
are reported and compared. Possible growth mechanisms which govern
the physical characteristics of the ZnO nanostructures synthesized
in the HTG process are proposed and discussed