Microscopic Investigation on Morphologies of Bilayer Gel Structure in the Mixed Polyoxyethylene-Type Nonionic Surfactant Systems

Abstract

We investigated morphologies of lamellar domains below the Krafft temperature in the mixed polyoxyethylene-type nonionic surfactant, a C<sub>16</sub>E<sub>6</sub>/C<sub>16</sub>E<sub>7</sub>/water system, by using optical microscopy, confocal microscopy, small/wide-angle X-ray scattering, and small-angle neutron scattering. We have found that the morphology discontinuously changes from network structures of lamellar domains to spherical vesicles with increasing mole fraction of C<sub>16</sub>E<sub>7</sub>, via the coexistence region of vesicles and network structures of lamellar domains

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