Cascade Molecule–Particle–Molecule
Self-Assemblies
for Fabricating Narrowly Size-Distributed Polymeric Superparticles
with a Bicontinuous Nanostructure
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Abstract
Broader developments of nanoscience and nanotechnology
require
complexly but regularly structured nanoparticles whose fabrications
in turn pose a great challenge to nanoscience and nanotechnology.
In this communication, we report a new and robust method with a clear
mechanism for fabricating narrowly size-distributed superparticles
with a bicontinuous inner structure. The processes for the fabrication
include: molecular self-assembly of a triblock copolymer in its selective
solvent into the core–shell–corona micelles, the self-limited
aggregation of the micelles (particles)
into narrowly size-distributed superparticles constructed by the integrated
micelles, and the final molecular self-assembly confined within the
superparticles into cylinders that are crowded and interconnected
to form the bicontinuous nanostructure; the molecular self-assembly
into the micelles, the self-limited aggregation of the particles (i.e.,
the micelles), and the further molecular self-assembly within the
superparticles occurred in a cascade manner