Solution-Processed Inorganic–Organic Hybrid Electron Injection Layer for Polymer Light-Emitting Devices

Abstract

A lithium quinolate complex (Liq) has high solubility in polar solvents such as alcohols and can be spin-coated onto emitting polymers, resulting in a smooth surface morphology. A polymer light-emitting device fabricated with spin-coated Liq as an electron injection layer (EIL) exhibited a lower turn-on voltage and a higher efficiency than a device with spin-coated Cs₂CO₃ and a device with thermally evaporated Ca. The mixture of ZnO nanoparticles and Liq served as an efficient EIL, resulting in a lower driving voltage even in thick films (∼10 nm), and it did not require a high-temperature annealing process