n‑Type Naphthalene
Diimide–Biselenophene
Copolymer for All-Polymer Bulk Heterojunction Solar Cells
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Abstract
A new solution processable n-type polymer semiconductor
is synthesized
and characterized for use as an electron acceptor material in all-polymer
bulk heterojunction solar cells. The new crystalline copolymer, poly(naphthalene
diimide-<i>alt</i>-biselenophene) (PNDIBS), has a high field-effect
electron mobility (0.07 cm<sup>2</sup>/(V s)) and broad visible-near-infrared
absorption band with an optical band gap of 1.4 eV. All-polymer bulk
heterojunction solar cells comprised of PNDIBS acceptor and poly(3-hexylthiophene)
donor have a photovoltaic power conversion efficiency of 0.9%. The
external quantum efficiency spectrum of the all-polymer solar cells
shows that about 19% of the photocurrent comes from the near-infrared
(700–900 nm) light harvesting by the new n-type polymer semiconductor