Direct Synthesis of Bimetallic
Pd<sub>3</sub>Ag Nanoalloys from Bulk Pd<sub>3</sub>Ag Alloy
- Publication date
- Publisher
Abstract
We report a transformative, all inorganic synthesis method
of preparing supported bimetallic Pd<sub>3</sub>Ag alloy nanoparticles.
The method involves breaking down bulk Pd<sub>3</sub>Ag alloy into
the nanoparticles in liquid lithium, converting metallic Li to LiOH,
and transferring Pd<sub>3</sub>Ag nanoparticles/LiOH mixture onto
non-water-soluble supports, followed by leaching off the LiOH with
water under ambient conditions. The size of the resulting Pd<sub>3</sub>Ag nanoparticles was found narrowly distributed around 2.3 nm characterized
by transmission electron microscope (TEM). In addition, studies by
X-ray diffraction (XRD), extended X-ray absorption fine structure
(EXAFS) spectroscopy, and X-ray absorption near edge structure (XANES)
spectroscopy showed that the resulting Pd<sub>3</sub>Ag nanoparticles
inherited similar atomic ratio and alloy structure as the starting
material. The synthesized Pd<sub>3</sub>Ag nanoparticles exhibited
excellent catalytic activity toward hydrogenation of acrolein to propanal