Novel Iron(II) Microporous
Spin-Crossover Coordination Polymers with Enhanced Pore Size
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Abstract
In this Communication, we report the synthesis and characterization
of novel Hofmann-like spin-crossover porous coordination polymers
of composition {Fe(L)[M(CN)<sub>4</sub>]}·G [L = 1,4-bis(4-pyridylethynyl)benzene
and M<sup>II</sup> = Ni, Pd, and Pt]. The spin-crossover properties
of the framework are closely related to the number and nature of the
guest molecules included in the pores
