2‑Pyrrolyloximes
in High-Nuclearity Transition-Metal Cluster Chemistry: Fe<sub>10</sub> and Fe<sub>12</sub>
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Abstract
The employment of 2-pyrrolyloximes in high-nuclearity
transition-metal cluster chemistry has provided access to unprecedented
decanuclear and dodecanuclear Fe<sup>III</sup> cagelike clusters bearing
the anion of pyrrole-2-carboxaldehyde oxime (praoH<sub>2</sub>), the
simplest member of this new family of ligands; the identity of the
products depends on the nature of the counteranion present in the
starting materials