Direct Access to Tetrahydro[1,2]diazepinones from α,β-Epoxy‑<i>N</i>‑aziridinylimines via Anionic Rearrangement

Abstract

A novel one-step synthetic approach to tetrahydro[1,2]diazepinones via base-promoted rearrangement of α,β-epoxy-<i>N</i>-aziridinylimines, derived from α,β-epoxyketones and <i>N</i>-aminoaziridines, has been developed