A Strategy for the Synthesis of Anthraquinone-Based
Aryl‑<i>C</i>‑glycosides
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Abstract
An efficient and simple strategy
for the synthesis of a diverse
range of anthraquinone-based aryl-<i>C</i>-glycosides has
been developed. It involves the sequential Diels–Alder reaction
and oxidative aromatization with the preformed glycosyl diene and
dienophiles. The glycosyl dienes were obtained from simple sugars
by tandem one-pot substitution and elimination reaction