Purposes of this research were to determine differences of participation and learning outcomes beetwen students were taught using TPS Cooperative learning model and conventional method and effect of applying TPS Cooperative learning model toward learning outcomes redox materials X Grade in High School of St. Francis of Assisi Pontianak. Quasi-experimental with nonequivalent control group design was used as research method. The sample were students X E as control class and X D as experimental class that were determined with purpossive sampling technique. Participation were analyzed using Independent Samples T-test and outcomes learning using U-Mann Whitney. The result of data analysis showed that there were differences participation and learning outcomes beetwen students were taught using cooperatif learning model TPS type and conventional method. TPS Cooperative learning model give effect in the amount of 26.11% on increasing students learning outcomes