An Unprecedented Decanuclear Gd<sup>III</sup> Cluster for Magnetic Refrigeration

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    Abstract

    An unprecedented decanuclear Gd<sup>III</sup> cluster composed of the [Gd<sub>10</sub>(μ<sub>3</sub>-OH)<sub>8</sub>]<sup>22+</sup> core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (−Δ<i>S</i><sub>m</sub><sup>max</sup> = 31.22 J kg<sup>–1</sup> K<sup>–1</sup>)

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      Last time updated on 12/02/2018