Tandem Isomerization and C–H Activation: Regioselective
Hydroheteroarylation of Allylarenes
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Abstract
The first Ni-promoted prototype reaction based on the tandem C–H
activation of heteroarenes with alkene isomerization is demonstrated,
leading to the branched hydroheteroarylation products. Simultaneously,
the reaction selectivity can be chemically switched to linear adducts
through Ni–Al tandem catalysis