Electrospun Hierarchical TiO₂ Nanorods with High Porosity for Efficient Dye-Sensitized Solar Cells

Abstract

Ultraporous anatase TiO₂ nanorods with a composite structure of mesopores and macropores fabricated via a simple microemulsion electrospinning approach were first used as photoanode materials for high-efficiency dye-sensitized solar cells (DSSCs). The special multiscale porous structure was formed by using low-cost paraffin oil microemulsion droplets as the soft template, which can not only provide enhanced adsorption sites for dye molecules but also facilitate the electrolyte diffusion. The morphology, porosity, and photovoltaic and electron dynamic characteristics of the porous TiO₂ nanorod based DSSCs were investigated in detail by scanning electron microscopy (SEM), N₂ sorption measurements, current density–voltage (<i>J</i>–<i>V</i>) curves, UV–vis diffuse reflectance spectra, electrochemical impedance spectroscopy (EIS), intensity modulated photocurrent/photovoltage spectroscopy (IMPS/IMVS), and open-circuit voltage decay (OCVD) measurements. The results revealed that, although fewer amounts of dyes were anchored on the porous TiO₂ nanorod films, they exhibited stronger light scattering ability, fast electrolyte diffusion, and extended electron lifetime compared to the commercial P25 nanoparticles. A power conversion efficiency of 6.07% was obtained for the porous TiO₂ nanorod based DSSCs. Moreover, this value can be further improved to 8.53% when bilayer structured photoanode with porous TiO₂ nanorods acting as the light scattering layer was constructed. This study demonstrated that the porous TiO₂ nanorods can work as promising photoanode materials for DSSCs