Metallosupramolecular Poly[2]pseudorotaxane Constructed by Metal Coordination and Crown-Ether-Based Molecular Recognition

Abstract

A novel bis­(<i>m</i>-phenylene)-32-crown-10 derivative bearing two π-extended pyridyl groups was synthesized, and its host–guest complexation with a paraquat derivative to form a threaded [2]­pseudorotaxane was studied. Subsequently, a poly[2]­pseudorotaxane was constructed with a metallosupramolecular polymer backbone via metal coordination, which was comprehensively confirmed by the combination of ¹H NMR, ³¹P­{¹H} NMR, DOSY NMR, DLS, and EDX techniques