Total Synthesis of Sandresolide B and Amphilectolide
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Abstract
The total synthesis
of the diterpenoids sandresolide B and amphilectolide
from a common furan building block is presented. Key steps include
palladium-mediated carbonylation, lanthanide catalyzed ring closure,
Myers alkylation, intramolecular Friedel–Crafts acylation,
photooxygenation, and a Kornblum–DeLaMare rearrangement