Double
C(sp<sup>3</sup>)–H Bond Functionalization
Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective
Construction of Polyheterocycles
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Abstract
Described herein
are two novel types of double C(sp<sup>3</sup>)–H bond functionalizations
triggered by a sequential hydride
shift/cyclization process: (1) construction of a bicyclo[3.2.2]nonane
skeleton by a [1,6]- and [1,5]-hydride shift sequence and (2) sequential
[1,4]- and [1,5]-hydride shift mediated construction of a linear tricyclic
skeleton