A Thienoisoindigo-Naphthalene
Polymer with Ultrahigh
Mobility of 14.4 cm<sup>2</sup>/V·s That Substantially Exceeds
Benchmark Values for Amorphous Silicon Semiconductors
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Abstract
By considering the qualitative benefits
associated with solution
rheology and mechanical properties of polymer semiconductors, it is
expected that polymer-based electronic devices will soon enter our
daily lives as indispensable elements in a myriad of flexible and
ultra low-cost flat panel displays. Despite more than a decade of
research focused on designing and synthesizing state-of-the-art polymer
semiconductors for improving charge transport characteristics, the
current mobility values are still not sufficient for many practical
applications. The confident mobility in excess of ∼10 cm<sup>2</sup>/V·s is the most important requirement for enabling the
realization of the aforementioned near-future products. We report
on an easily attainable donor–acceptor (D–A) polymer
semiconductor: poly(thienoisoindigo-<i>alt</i>-naphthalene)
(PTIIG-Np). An unprecedented mobility of 14.4 cm<sup>2</sup>/V·s,
by using PTIIG-Np with a high-<i>k</i> gate dielectric poly(vinylidenefluoride-trifluoroethylene)
(P(VDF-TrFE)), is achieved from a simple coating processing, which
is of a magnitude that is very difficult to obtain with conventional
TFTs by means of molecular engineering. This work, therefore, represents
a major step toward truly viable plastic electronics