Melilite
LaSrGa<sub>3−<i>x</i></sub>Al<sub><i>x</i></sub>O<sub>7</sub> Series: A Combined Solid-State
NMR and Neutron Diffraction Study
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Abstract
Oxides
characterized by a layered melilite structure, with general
formula ABT<sup>1</sup><sub>(1)</sub>T<sup>2</sup><sub>(2)</sub>O<sub>7</sub>, find applications in many different technological fields
due to their relevant magnetic, optical, and electrical properties.
These functional properties are, in turn, related to local features
such as structural defects and cation substitutions. Therefore, a
complete structural characterization of these complex anisotropic
compounds is mandatory, and the combined use of long-range (X-ray
and neutron diffraction) and short-range (solid state NMR) techniques
is a key approach to this aim. In this work, we present the full structural
characterization of the series LaSrGa<sub>3–<i>x</i></sub>Al<sub><i>x</i></sub>O<sub>7</sub> (<i>x</i> = 0, 1, 1.5, 2, and 3), which was obtained for the first time by
means of a new sol–gel approach. Analysis of neutron diffraction
data revealed that the distribution of La/Sr and Ga/Al on the respective
sites is random. <sup>27</sup>Al and <sup>71</sup>Ga solid state NMR
enabled us to rationalize the local structure of the T sites in terms
of nearest and next-nearest neighbors. This study provides a deep
structural insight that can be helpful for the understanding of the
functional properties and is a powerful strategy for the analysis
of complex oxide systems