Energy-Efficient Green Catalysis:
Supported Gold Nanoparticle-Catalyzed
Aminolysis of Esters with Inert Tertiary Amines by C–O and
C–N Bond Activations
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Abstract
Catalyzed
by supported gold nanoparticles, an aminolysis reaction
between various aryl esters and inert tertiary amines by C–O
and C–N bond activations has been developed for the selective
synthesis of tertiary amides. Comparison studies indicated that the
gold nanoparticles could perform energy-efficient green catalysis
at room temperature, whereas Pd(OAc)<sub>2</sub> could not