Synthesis and Characterization
of Quantum Dot Nanoparticles
Bound to the Plant Volatile Precursor of Hydroxy-apo-10′-carotenal
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Abstract
This study is focused on the synthesis
and characterization of
hydroxy-apo-10′-carotenal/quantum dot (QD) conjugates aiming
at the <i>in vivo</i> visualization of β-ionone, a
carotenoid-derived volatile compound known for its important contribution
to the flavor and aroma of many fruits, vegetables, and plants. The
synthesis of nanoparticles bound to plant volatile precursors was
achieved via coupling reaction of the QD to C<sub>27</sub>-aldehyde
which was prepared from α-ionone via 12 steps in 2.4% overall
yield. The formation of the QD-conjugate was confirmed by measuring
its fluorescence spectrum to observe the occurrence of fluorescence
resonance energy transfer