Efficient
Li<sub>2</sub>O<sub>2</sub> Formation via
Aprotic Oxygen Reduction Reaction Mediated by Quinone Derivatives
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Abstract
Since
the oxygen reduction reaction (ORR) in aprotic Li ion electrolytes
accompanied by Li<sub>2</sub>O<sub>2</sub> formation is a crucial
reaction for the discharge of nonaqueous aprotic Li–air batteries,
there is a strong demand for a reduction in the overpotential of the
reaction in order to improve the discharge performance. In the present
work, we investigated the effect of the addition of quinone derivatives
for ORR on carbon materials in aprotic Li<sup>+</sup>–electrolytes.
Detailed electrochemical analysis revealed that the semiquinone species
catalyze the aprotic ORR, resulting in the efficient Li<sub>2</sub>O<sub>2</sub> formation. Among the quinone derivatives, benzoquinone
exhibited the best catalytic performance, with an overpotential for
the Li<sub>2</sub>O<sub>2</sub> formation of less than 100 mV